In situ ambient pressure XPS study of CO oxidation reaction on Pd(111) surfaces

Ryo Toyoshima, Masaaki Yoshida, Yuji Monya, Yuka Kousa, Kazuma Suzuki, Hitoshi Abe, Bongjin Simon Mun, Kazuhiko Mase, Kenta Amemiya, Hiroshi Kondoh

研究成果: Article査読

105 被引用数 (Scopus)

抄録

The CO oxidation reaction on the Pd(111) model catalyst at various temperatures (200-400 °C) under hundreds mTorr pressure conditions has been monitored by in situ ambient pressure X-ray photoelectron spectroscopy and mass spectroscopy. In situ observation of the reaction revealed that the Pd(111) surface is covered by CO molecules at a lower temperature (200 °C), while at higher temperatures (300-400 °C) several oxide phases are formed on the surface. We found that the reactivity is enhanced in the presence of a surface oxide and significantly suppressed by formation of a cluster oxide and the PdO bulk oxide. CO titration experiments suggest that less coordinated oxygen atoms are more reactive for CO oxidation.

本文言語English
ページ(範囲)18691-18697
ページ数7
ジャーナルJournal of Physical Chemistry C
116
35
DOI
出版ステータスPublished - 2012 9 6

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

フィンガープリント 「In situ ambient pressure XPS study of CO oxidation reaction on Pd(111) surfaces」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル