In Situ Generation of Ruthenium Carbonyl Phosphine Complexes as a Versatile Method for the Development of Enantioselective C−O Bond Arylation

研究成果: Article査読

1 被引用数 (Scopus)

抄録

We report here a method for in situ generation of various ruthenium carbonyl phosphine catalysts for arylation via cleavage of inert aromatic carbon–oxygen bonds. The use of catalyst systems consisting of [RuCl2(CO)(p-cymene)], CsF, styrene, and phosphines enabled facile screening of phosphine ligands. Asymmetric C–O arylation was also achieved for atropo-enantioselective biaryl synthesis using a chiral monodentate phosphine ligand.

本文言語English
ページ(範囲)1737-1741
ページ数5
ジャーナルChemistry - A European Journal
26
8
DOI
出版ステータスPublished - 2020 2 6

ASJC Scopus subject areas

  • 触媒
  • 有機化学

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