In situ S-K XANES study of polymer electrolyte fuel cells: Changes in the chemical states of sulfonic groups depending on humidity

Kazuhisa Isegawa, Tetsuo Nagami, Shinji Jomori, Masaaki Yoshida, Hiroshi Kondoh

研究成果: Article

7 引用 (Scopus)

抄録

Changes in the chemical states of sulfonic groups of Nafion in polymer electrolyte fuel cells (PEFCs) under gas-flowing conditions were studied using in situ S-K XANES spectroscopy. The applied potential to the electrodes and the humidity of the cell were changed under flowing H2 gas in the anode and He gas in the cathode. While the potential shows no significant effect on the S-K XANES spectra, the humidity is found to induce reversible changes in the spectra. Comparison of the spectral changes with simulations based on the density functional theory calculations indicates that the humidity influences the chemical state of the sulfonic group; under wet conditions the sulfonic group is in the form of a sulfonate ion. By drying treatment the sulfonate ion binds to hydrogen and becomes sulfonic acid. Furthermore, a small fraction of the sulfonic acid irreversibly decomposes to atomic sulfur. The peak energy of the atomic sulfur suggests that the generated atomic sulfur is adsorbed on the Pt catalyst surfaces.

元の言語English
ページ(範囲)25183-25190
ページ数8
ジャーナルPhysical Chemistry Chemical Physics
18
発行部数36
DOI
出版物ステータスPublished - 2016

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Sulfur
Electrolytes
fuel cells
humidity
Fuel cells
Atmospheric humidity
Polymers
sulfur
Sulfonic Acids
Gases
sulfonic acid
electrolytes
sulfonates
polymers
gases
Ions
X ray absorption near edge structure spectroscopy
drying
Density functional theory
Hydrogen

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

これを引用

In situ S-K XANES study of polymer electrolyte fuel cells : Changes in the chemical states of sulfonic groups depending on humidity. / Isegawa, Kazuhisa; Nagami, Tetsuo; Jomori, Shinji; Yoshida, Masaaki; Kondoh, Hiroshi.

:: Physical Chemistry Chemical Physics, 巻 18, 番号 36, 2016, p. 25183-25190.

研究成果: Article

Isegawa, Kazuhisa ; Nagami, Tetsuo ; Jomori, Shinji ; Yoshida, Masaaki ; Kondoh, Hiroshi. / In situ S-K XANES study of polymer electrolyte fuel cells : Changes in the chemical states of sulfonic groups depending on humidity. :: Physical Chemistry Chemical Physics. 2016 ; 巻 18, 番号 36. pp. 25183-25190.
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