Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer

Masaaki Mitsui, Shingo Doi, Kaori Ikemoto, Shuhei Nagaoka, Atsushi Nakajima

研究成果: Chapter

抄録

Gas-phase synthesized vanadium-mesitylene 1:2 V(mes)2 cluster cations were size-selectively deposited onto a long-chain alkanethiolate selfassembled monolayer-coated gold substrate under ultrahigh vacuum conditions. Examination of the resultant clusters was conducted by infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD), showing the clusters molecularly adsorbed and maintaining a sandwich structure on the substrate.

本文言語English
ホスト出版物のタイトルLatest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale
出版社Imperial College Press
ページ199-204
ページ数6
ISBN(印刷版)9781848162389, 9781848162372
DOI
出版ステータスPublished - 2008 1 1

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)
  • Chemistry(all)
  • Physics and Astronomy(all)

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