Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes

Masaki Okamoto; Satoshi Onodera; Tomoki Okano; Eiichi Suzuki; Yoshio Ono

doi:10.1016/S0022-328X(96)06713-7

Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes

Masaki Okamoto, Satoshi Onodera, Tomoki Okano, Eiichi Suzuki, Yoshio Ono

研究成果: Article › 査読

29 被引用数 (Scopus)

抄録

The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.

本文言語	English
ページ（範囲）	67-71
ページ数	5
ジャーナル	Journal of Organometallic Chemistry
巻	531
号	1-2
DOI	https://doi.org/10.1016/S0022-328X(96)06713-7
出版ステータス	Published - 1997 3月 15
外部発表	はい

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学
無機化学
材料化学

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10.1016/S0022-328X(96)06713-7

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title = "Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes",

abstract = "The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.",

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author = "Masaki Okamoto and Satoshi Onodera and Tomoki Okano and Eiichi Suzuki and Yoshio Ono",

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T1 - Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes

AU - Okamoto, Masaki

AU - Onodera, Satoshi

AU - Okano, Tomoki

AU - Suzuki, Eiichi

AU - Ono, Yoshio

PY - 1997/3/15

Y1 - 1997/3/15

N2 - The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.

AB - The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.

KW - Alkyl halide

KW - Catalysis

KW - Copper

KW - Silane

KW - Silicon

KW - Silylene

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DO - 10.1016/S0022-328X(96)06713-7

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Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes

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