Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes

Masaki Okamoto, Satoshi Onodera, Tomoki Okano, Eiichi Suzuki, Yoshio Ono

研究成果: Article

26 引用 (Scopus)

抜粋

The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.

元の言語English
ページ(範囲)67-71
ページ数5
ジャーナルJournal of Organometallic Chemistry
531
発行部数1-2
DOI
出版物ステータスPublished - 1997 3 15
外部発表Yes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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