Intramolecular cyclization of m-homoprenylphenols through oxidative nucleophilic aromatic substitution

Hiroki Deguchi; Kengo Hanaya; Takeshi Sugai; Shuhei Higashibayashi

doi:10.1039/d2cc06026d

Intramolecular cyclization of m-homoprenylphenols through oxidative nucleophilic aromatic substitution

Hiroki Deguchi, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi

薬科学科

研究成果: Article › 査読

抄録

We developed an intramolecular cyclization of m-homoprenylphenols and related m-prenylphenols to bicyclic skeletons by hypervalent iodine reagents through an oxidative nucleophilic aromatic substitution using the prenyl group as a carbon nucleophile. The reaction was applicable for the syntheses of 5/6-, 6/6-, and 7/6-fused ring systems.

本文言語	English
ページ（範囲）	748-751
ページ数	4
ジャーナル	Chemical Communications
巻	59
号	6
DOI	https://doi.org/10.1039/d2cc06026d
出版ステータス	Published - 2022 12月 15

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/d2cc06026d

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abstract = "We developed an intramolecular cyclization of m-homoprenylphenols and related m-prenylphenols to bicyclic skeletons by hypervalent iodine reagents through an oxidative nucleophilic aromatic substitution using the prenyl group as a carbon nucleophile. The reaction was applicable for the syntheses of 5/6-, 6/6-, and 7/6-fused ring systems.",

author = "Hiroki Deguchi and Kengo Hanaya and Takeshi Sugai and Shuhei Higashibayashi",

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AU - Deguchi, Hiroki

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AU - Sugai, Takeshi

AU - Higashibayashi, Shuhei

PY - 2022/12/15

Y1 - 2022/12/15

N2 - We developed an intramolecular cyclization of m-homoprenylphenols and related m-prenylphenols to bicyclic skeletons by hypervalent iodine reagents through an oxidative nucleophilic aromatic substitution using the prenyl group as a carbon nucleophile. The reaction was applicable for the syntheses of 5/6-, 6/6-, and 7/6-fused ring systems.

AB - We developed an intramolecular cyclization of m-homoprenylphenols and related m-prenylphenols to bicyclic skeletons by hypervalent iodine reagents through an oxidative nucleophilic aromatic substitution using the prenyl group as a carbon nucleophile. The reaction was applicable for the syntheses of 5/6-, 6/6-, and 7/6-fused ring systems.

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Intramolecular cyclization of m-homoprenylphenols through oxidative nucleophilic aromatic substitution

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