Introduction of three aryl groups to benzotriazinyl radical by suzukimiyaura cross-coupling reaction

Yusuke Takahashi, Youhei Miura, Naoki Yoshioka

研究成果: Article査読

26 被引用数 (Scopus)

抄録

A new radical, 7-phenyl-1,3-bis(4-biphenylyl)-1,4-dihydro-1,2,4-benzotriazin-4-yl (2), was prepared from the iodo groupsubstituted benzotriazinyl radical 1 with phenyltriolborate salt by the SuzukiMiyaura cross-coupling reaction at room temperature. An X-ray crystal structural analysis clarified its crystal structure. ESR measurements and DFT calculations revealed that its unpaired electron was more delocalized over the molecule than that of Blatter's radical due to the substituent effect.

本文言語English
ページ(範囲)1236-1238
ページ数3
ジャーナルChemistry Letters
43
8
DOI
出版ステータスPublished - 2014

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「Introduction of three aryl groups to benzotriazinyl radical by suzukimiyaura cross-coupling reaction」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル