Investigation of nitro-nitrito photoisomerization: Crystal structure of trans-chloridonitro(1,4,8,11-tetraazacyclotetradecane-κ4 N,N′,N′′,N′′′)cobalt(III) chloride

Shigeru Ohba, Masanobu Tsuchimoto, Naoki Yamada

研究成果: Article査読

抄録

The reaction cavity of the nitro group in the crystal of the title compound, [CoCl(NO2)(C10H24N4)]Cl, (I), was investigated to confirm that it offers sufficient free space for linkage isomerization to occur in accordance with the observed photochemical reactivity. The complex cation has crystallographic 2/m symmetry and the nitro and chloro ligands at the trans positions are statistically disordered. The complete cyclam ligand is generated by symmetry from a quarter of the molecule. In the crystal of (I), the complex cations and Cl- ions are linked into a three-dimensional network by N - H⋯Cl(counter-ion) hydrogen bonds.

本文言語English
ページ(範囲)1908-1912
ページ数5
ジャーナルActa Crystallographica Section E: Crystallographic Communications
74
DOI
出版ステータスPublished - 2018

ASJC Scopus subject areas

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学

フィンガープリント

「Investigation of nitro-nitrito photoisomerization: Crystal structure of trans-chloridonitro(1,4,8,11-tetraazacyclotetradecane-κ<sup>4</sup> N,N′,N′′,N′′′)cobalt(III) chloride」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル