Ion-paired chromatographic separation of iron(II) complexes of 1,10-phenanthroline and its derivatives

Mudasir, Naoki Yoshioka, Hidenari Inoue

研究成果: Article査読

12 被引用数 (Scopus)

抄録

Iron(II) chelate complexes of 1,10-phenanthroline (Phen), 4,7-dimethyl-1,10-phenanthroline (DMPhen), 3,4,7,8-tetramethyl-1,10-phenanthroline (TMPhen) and 4,7-diphenyl(batho)-1,10-phenanthroline (DPPhen) were prepared and identified by means of absorption and infrared spectroscopy. The characteristic elution of these complexes on an Inertsil ODS column as well as their separation was investigated by ion-paired reversed phase chromatography. Some parameters influencing the separation such as composition of eluent, counter ion species and their concentrations were also studied. It was found that acetonitrile/water (80/20,v/v) containing 0.06 M HClO4 gave the best separation for each complex.

本文言語English
ページ(範囲)2239-2254
ページ数16
ジャーナルAnalytical Letters
29
12
DOI
出版ステータスPublished - 1996

ASJC Scopus subject areas

  • 分析化学
  • 生化学
  • 分光学
  • 臨床生化学
  • 生化学、医学
  • 電気化学

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