Large nonlinear effect observed in the enantiomeric excess of proline in solution and that in the solid state

Yujiro Hayashi, Masayoshi Matsuzawa, Junichiro Yamaguchi, Sayaka Yonehara, Yasunobu Matsumoto, Mitsuru Shoji, Daisuke Hashizume, Hiroyuki Koshino

研究成果: Article査読

91 被引用数 (Scopus)

抄録

(Chemical Equation Presented) A clue to the origin of chirality? A solution of proline with high enantiomeric excess (85-99% ee) was obtained from solid proline of only 10% ee through novel dissolution and crystallization processes (see scheme). This observation may be an explanation for the origin of chirality on Earth.

本文言語English
ページ(範囲)4593-4597
ページ数5
ジャーナルAngewandte Chemie - International Edition
45
28
DOI
出版ステータスPublished - 2006 7 10

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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