Light-induced O-glycosylation of unprotected deoxythioglycosyl donors

研究成果: Article査読

34 被引用数 (Scopus)

抄録

The O-glycosylation of several unprotected deoxythioglycosides and alcohols using 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) under long-wavelength UV irradiation was effectively realized using a single electron transfer (SET) mechanism. In some cases, the use of p-methoxyboronic acid was very effective in temporary protection of the 1,3-diol (C4 and C6 positions) of the unprotected glycosyl donors to increase the yields of the obtained O-glycosides.

本文言語English
ページ(範囲)5079-5082
ページ数4
ジャーナルOrganic and Biomolecular Chemistry
11
31
DOI
出版ステータスPublished - 2013 8 21

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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