Lipase-catalyzed ring-opening polymerization of β-butyrolactone to the cyclic and linear poly(3-hydroxybutyrate)

Shuichi Matsumura, Yoichi Suzuki, Keisuke Tsukada, Kazunobu Toshima, Yoshiharu Doi, Ken Ichi Kasuya

研究成果: Article査読

52 被引用数 (Scopus)

抄録

The four-membered β-butyrolactone (BL) was polymerized using a ring-opening polymerization reaction with lipase as a catalyst at a temperature between 60 and 100 °C to yield the corresponding cyclic and linear poly(3-hydroxybutyrate)s [P(3HB)] with weight-average molecular weights of up to 7300. Among the tested lipases, porcine pancreatic lipase (PPL) and Candida cylindracea lipase (CC) showed the best results with respect to the molecular weight of the resulting polymer and the monomer conversion. It was found that a significant amount of the cyclic P(3HB) fraction in the resulting polymer was produced and the cyclic polymer was increased with increasing monomer conversion. The (R)-BL was more easily polymerized by lipase to form the corresponding P(3HB) having a higher molecular weight than that formed by using (R,S)-BL.

本文言語English
ページ(範囲)6444-6449
ページ数6
ジャーナルMacromolecules
31
19
DOI
出版ステータスPublished - 1998 9月 22

ASJC Scopus subject areas

  • 有機化学
  • ポリマーおよびプラスチック
  • 無機化学
  • 材料化学

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