Lithiation of 1,2-dichloroethene in flow microreactors: Versatile synthesis of alkenes and alkynes by precise residence-time control

Aiichiro Nagaki, Chika Matsuo, Songhee Kim, Kodai Saito, Atsuo Miyazaki, Jun Ichi Yoshida

研究成果: Article査読

78 被引用数 (Scopus)

抄録

It′s all about the timing: Precise control of the residence time (t Rx; see picture) of reactive intermediates in flow microreactors enables the reaction pathway of lithiated 1,2-dichloroethene to be switched to produce either alkenes or alkynes. This method also allows versatile syntheses of asymmetric disubstituted dichloroalkenes and alkynes.

本文言語English
ページ(範囲)3245-3248
ページ数4
ジャーナルAngewandte Chemie - International Edition
51
13
DOI
出版ステータスPublished - 2012 3 26
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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