Living ring-opening polymerization of cyclic carbonate using cationic zirconocene complex as catalyst

Michiya Hayakawa; Makoto Mitani; Tohru Yamada; Teruaki Mukaiyama

Living ring-opening polymerization of cyclic carbonate using cationic zirconocene complex as catalyst

Michiya Hayakawa, Makoto Mitani, Tohru Yamada, Teruaki Mukaiyama

研究成果: Article › 査読

抄録

Living ring-opening polymerization of the cyclic carbonate 1,3-dioxepan-2-one was achieved by using the cationic zirconocene complex [Cp₂ZrMe]⁺[B(C₆F₅)₄] ^- as catalyst at room temperature. A linear relation between conversion and molecular weight of the obtained polymer was observed. Furthermore, block copolymerization of the cyclic carbonate and ε-caprolactone was successfully performed.

本文言語	English
ページ（範囲）	865-870
ページ数	6
ジャーナル	Macromolecular Rapid Communications
巻	17
号	12
出版ステータス	Published - 1996 12月 1
外部発表	はい

ASJC Scopus subject areas

有機化学
ポリマーおよびプラスチック
材料化学

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引用スタイル

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title = "Living ring-opening polymerization of cyclic carbonate using cationic zirconocene complex as catalyst",

abstract = "Living ring-opening polymerization of the cyclic carbonate 1,3-dioxepan-2-one was achieved by using the cationic zirconocene complex [Cp2ZrMe]+[B(C6F5)4] - as catalyst at room temperature. A linear relation between conversion and molecular weight of the obtained polymer was observed. Furthermore, block copolymerization of the cyclic carbonate and ε-caprolactone was successfully performed.",

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N2 - Living ring-opening polymerization of the cyclic carbonate 1,3-dioxepan-2-one was achieved by using the cationic zirconocene complex [Cp2ZrMe]+[B(C6F5)4] - as catalyst at room temperature. A linear relation between conversion and molecular weight of the obtained polymer was observed. Furthermore, block copolymerization of the cyclic carbonate and ε-caprolactone was successfully performed.

AB - Living ring-opening polymerization of the cyclic carbonate 1,3-dioxepan-2-one was achieved by using the cationic zirconocene complex [Cp2ZrMe]+[B(C6F5)4] - as catalyst at room temperature. A linear relation between conversion and molecular weight of the obtained polymer was observed. Furthermore, block copolymerization of the cyclic carbonate and ε-caprolactone was successfully performed.

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Living ring-opening polymerization of cyclic carbonate using cationic zirconocene complex as catalyst

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ASJC Scopus subject areas

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