Mössbauer study on photochemistry of ferrocene isolated in low-temperature matrix

Y. Einaga, Y. Yamada, T. Tominaga

研究成果: Article

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Unstable novel species produced by photolysis of ferrocene (Cp2Fe) isolated in low-temperature matrix were studied by means of the 57Fe Mössbauer spectroscopy. On the UV-irradiation of 57Fe-enriched ferrocene co-condensed with CCl4 in low-temperature ^ matrix (20 K), unknown high spin ferrous species (I.S. = 0.90 ± 0.01 mm/s, Q.S. = 1.94 ± 0.02 mm/s) were produced as well as ferricinium ion [Cp2Fe]+ (I.S. = 0.52 ± 0.01 mm/s, Q.S. = 0.0 mm/s). On the annealing, these photoproducts disappeared to reform ferrocene by the reverse reaction in the matrix. The mechanisms of the photochemical reaction were discussed.

元の言語English
ページ(範囲)97-100
ページ数4
ジャーナルJournal of Radioanalytical and Nuclear Chemistry
218
発行部数1
DOI
出版物ステータスPublished - 1997 1 1
外部発表Yes

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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