Microwave specific effect on catalytic enantioselective reactions

研究成果: Conference contribution

抄録

The microwave specific effect was investigated on the catalytic enantioselective reactions; atropo-enantiveselective ring-opening reaction of biaryl lactones and enantioselective Claisen rearrangement reaction. These reactions were efficiently enhanced with microwave irradiation under reaction temperature control, thought any loss of the enantioselectivities were not detected. It was also found that the racemization rate of the atropo-optically active biaryl lactone was enhanced by microwave irradiation. As these observations could not be explained by the simple thermal effect, microwave specific effect should be considered.

本文言語English
ホスト出版物のタイトル2018 Asia-Pacific Microwave Conference, APMC 2018 - Proceedings
出版社Institute of Electrical and Electronics Engineers Inc.
ページ1627-1629
ページ数3
ISBN(電子版)9784902339451
DOI
出版ステータスPublished - 2019 1 16
イベント30th Asia-Pacific Microwave Conference, APMC 2018 - Kyoto, Japan
継続期間: 2018 11 62018 11 9

出版物シリーズ

名前Asia-Pacific Microwave Conference Proceedings, APMC
2018-November

Conference

Conference30th Asia-Pacific Microwave Conference, APMC 2018
CountryJapan
CityKyoto
Period18/11/618/11/9

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

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