Mild manganese(III) acetate catalyzed allylic oxidation: Application to simple and complex alkenes

Tony K.M. Shing; Ying Yeung Yeung; Pak L. Su

doi:10.1021/ol0612298

Mild manganese(III) acetate catalyzed allylic oxidation: Application to simple and complex alkenes

Tony K.M. Shing, Ying Yeung Yeung, Pak L. Su

化学科

研究成果: Article › 査読

168 被引用数 (Scopus)

抄録

Manganese(III) acetate catalyzed allylic oxidation of alkenes to the corresponding enones was investigated, showing excellent regioselectivity and chemoselectivity (functional group compatibility). Δ⁵-Steroids were transformed into bioactive Δ⁵-en-7-ones under a nitrogen atmosphere, whereas simple alkenes were converted into the corresponding enones under an oxygen atmosphere in good yields.

本文言語	English
ページ（範囲）	3149-3151
ページ数	3
ジャーナル	Organic Letters
巻	8
号	14
DOI	https://doi.org/10.1021/ol0612298
出版ステータス	Published - 2006 7月 6

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol0612298

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abstract = "Manganese(III) acetate catalyzed allylic oxidation of alkenes to the corresponding enones was investigated, showing excellent regioselectivity and chemoselectivity (functional group compatibility). Δ5-Steroids were transformed into bioactive Δ5-en-7-ones under a nitrogen atmosphere, whereas simple alkenes were converted into the corresponding enones under an oxygen atmosphere in good yields.",

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AB - Manganese(III) acetate catalyzed allylic oxidation of alkenes to the corresponding enones was investigated, showing excellent regioselectivity and chemoselectivity (functional group compatibility). Δ5-Steroids were transformed into bioactive Δ5-en-7-ones under a nitrogen atmosphere, whereas simple alkenes were converted into the corresponding enones under an oxygen atmosphere in good yields.

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Mild manganese(III) acetate catalyzed allylic oxidation: Application to simple and complex alkenes

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