抄録
Saddle in a spin: The saddle-shaped octaethyltetraphenylporphyrin-imidazole complex [FeIII (oetpp)(HIm)]+ adopts an essentially pure intermediate-spin state between 298 and 173 K in CD2Cl2 solution, the conditions under which the NMR spectra are recorded. This complex has shown, however, a novel spin transition from S=3/2 to S=5/2 and S=1/2 below 70 K. Thus, the complex exists as an equilibrium mixture of three spin isomers at 4 K.
本文言語 | English |
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ページ(範囲) | 6300-6303 |
ページ数 | 4 |
ジャーナル | Angewandte Chemie - International Edition |
巻 | 48 |
号 | 34 |
DOI | |
出版ステータス | Published - 2009 8月 10 |
ASJC Scopus subject areas
- 触媒
- 化学 (全般)