Molecular complexes of anionic porphyrin and anionic aromatics

Toshinori Sato; Teiichiro Ogawa; Koji Kano

doi:10.1021/j150660a060

Molecular complexes of anionic porphyrin and anionic aromatics

Toshinori Sato, Teiichiro Ogawa, Koji Kano

研究成果: Article › 査読

16 被引用数 (Scopus)

抄録

Absorption and fluorescence emission spectra indicated that an anionic porphyrin, 5-phenyl-10,15,20-tris(p-sulfonatophenyl)porphine (TPPS₃^-), in water formed ground-state complexes with various anionic aromatics. The thermodynamic parameters (ΔH and ΔS) for complexation suggested that a van der Waals interaction is the predominant binding force and a hydrophobic interaction assists the stabilization of the complexes.

本文言語	English
ページ（範囲）	3678-3682
ページ数	5
ジャーナル	Journal of Physical Chemistry
巻	88
号	16
DOI	https://doi.org/10.1021/j150660a060
出版ステータス	Published - 1984
外部発表	はい

ASJC Scopus subject areas

工学（全般）
物理化学および理論化学

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10.1021/j150660a060

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title = "Molecular complexes of anionic porphyrin and anionic aromatics",

abstract = "Absorption and fluorescence emission spectra indicated that an anionic porphyrin, 5-phenyl-10,15,20-tris(p-sulfonatophenyl)porphine (TPPS3-), in water formed ground-state complexes with various anionic aromatics. The thermodynamic parameters (ΔH and ΔS) for complexation suggested that a van der Waals interaction is the predominant binding force and a hydrophobic interaction assists the stabilization of the complexes.",

author = "Toshinori Sato and Teiichiro Ogawa and Koji Kano",

year = "1984",

doi = "10.1021/j150660a060",

language = "English",

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pages = "3678--3682",

journal = "Journal of Physical Chemistry",

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publisher = "American Chemical Society",

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T1 - Molecular complexes of anionic porphyrin and anionic aromatics

AU - Sato, Toshinori

AU - Ogawa, Teiichiro

AU - Kano, Koji

PY - 1984

Y1 - 1984

N2 - Absorption and fluorescence emission spectra indicated that an anionic porphyrin, 5-phenyl-10,15,20-tris(p-sulfonatophenyl)porphine (TPPS3-), in water formed ground-state complexes with various anionic aromatics. The thermodynamic parameters (ΔH and ΔS) for complexation suggested that a van der Waals interaction is the predominant binding force and a hydrophobic interaction assists the stabilization of the complexes.

AB - Absorption and fluorescence emission spectra indicated that an anionic porphyrin, 5-phenyl-10,15,20-tris(p-sulfonatophenyl)porphine (TPPS3-), in water formed ground-state complexes with various anionic aromatics. The thermodynamic parameters (ΔH and ΔS) for complexation suggested that a van der Waals interaction is the predominant binding force and a hydrophobic interaction assists the stabilization of the complexes.

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U2 - 10.1021/j150660a060

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Molecular complexes of anionic porphyrin and anionic aromatics

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