抄録
The minimum structure of a poly(vinyl alcohol) block as a biodegradable segment in the polymer chain was estimated with respect to block length and its stereochemical configuration. It was found that poly(vinyl alcohol) block with a chain length of more than 3 monomeric units and having an isotactic structure is quickly biodegraded, in contrast to an atactic block having the same chain length, by poly(vinyl alcohol) (PVA) assimilating microbes and PVA‐dehydrogenase. It was also found that the substrate specificity of PVA‐dehydrogenase obtained from both Alcaligenes faecalis KK314 and Pseudomonas sp. 113 P3 is quite similar.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 3437-3445 |
| ページ数 | 9 |
| ジャーナル | Macromolecular Chemistry and Physics |
| 巻 | 196 |
| 発行部数 | 11 |
| DOI | |
| 出版物ステータス | Published - 1995 |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Organic Chemistry
- Polymers and Plastics
- Materials Chemistry
これを引用
Molecular design of biodegradable functional polymers, 4 Poly(vinyl alcohol) block as biodegradable segment. / Matsumura, Shuichi; Shimura, Yukimasa; Toshima, Kazunobu; Tsuji, Masao; Hatanaka, Tadashi.
：: Macromolecular Chemistry and Physics, 巻 196, 番号 11, 1995, p. 3437-3445.研究成果: Article
}
TY - JOUR
T1 - Molecular design of biodegradable functional polymers, 4 Poly(vinyl alcohol) block as biodegradable segment
AU - Matsumura, Shuichi
AU - Shimura, Yukimasa
AU - Toshima, Kazunobu
AU - Tsuji, Masao
AU - Hatanaka, Tadashi
PY - 1995
Y1 - 1995
N2 - The minimum structure of a poly(vinyl alcohol) block as a biodegradable segment in the polymer chain was estimated with respect to block length and its stereochemical configuration. It was found that poly(vinyl alcohol) block with a chain length of more than 3 monomeric units and having an isotactic structure is quickly biodegraded, in contrast to an atactic block having the same chain length, by poly(vinyl alcohol) (PVA) assimilating microbes and PVA‐dehydrogenase. It was also found that the substrate specificity of PVA‐dehydrogenase obtained from both Alcaligenes faecalis KK314 and Pseudomonas sp. 113 P3 is quite similar.
AB - The minimum structure of a poly(vinyl alcohol) block as a biodegradable segment in the polymer chain was estimated with respect to block length and its stereochemical configuration. It was found that poly(vinyl alcohol) block with a chain length of more than 3 monomeric units and having an isotactic structure is quickly biodegraded, in contrast to an atactic block having the same chain length, by poly(vinyl alcohol) (PVA) assimilating microbes and PVA‐dehydrogenase. It was also found that the substrate specificity of PVA‐dehydrogenase obtained from both Alcaligenes faecalis KK314 and Pseudomonas sp. 113 P3 is quite similar.
UR - http://www.scopus.com/inward/record.url?scp=0009353428&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0009353428&partnerID=8YFLogxK
U2 - 10.1002/macp.1995.021961101
DO - 10.1002/macp.1995.021961101
M3 - Article
AN - SCOPUS:0009353428
VL - 196
SP - 3437
EP - 3445
JO - Macromolecular Chemistry and Physics
JF - Macromolecular Chemistry and Physics
SN - 1022-1352
IS - 11
ER -