Molecular design of biodegradable functional polymers, 4 Poly(vinyl alcohol) block as biodegradable segment

Shuichi Matsumura, Yukimasa Shimura, Kazunobu Toshima, Masao Tsuji, Tadashi Hatanaka

研究成果: Article

8 引用 (Scopus)

抄録

The minimum structure of a poly(vinyl alcohol) block as a biodegradable segment in the polymer chain was estimated with respect to block length and its stereochemical configuration. It was found that poly(vinyl alcohol) block with a chain length of more than 3 monomeric units and having an isotactic structure is quickly biodegraded, in contrast to an atactic block having the same chain length, by poly(vinyl alcohol) (PVA) assimilating microbes and PVA‐dehydrogenase. It was also found that the substrate specificity of PVA‐dehydrogenase obtained from both Alcaligenes faecalis KK314 and Pseudomonas sp. 113 P3 is quite similar.

元の言語English
ページ(範囲)3437-3445
ページ数9
ジャーナルMacromolecular Chemistry and Physics
196
発行部数11
DOI
出版物ステータスPublished - 1995

Fingerprint

Functional polymers
Biodegradable polymers
alcohols
Alcohols
Chain length
polymers
pseudomonas
microorganisms
Polymers
Substrates
configurations

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

これを引用

Molecular design of biodegradable functional polymers, 4 Poly(vinyl alcohol) block as biodegradable segment. / Matsumura, Shuichi; Shimura, Yukimasa; Toshima, Kazunobu; Tsuji, Masao; Hatanaka, Tadashi.

:: Macromolecular Chemistry and Physics, 巻 196, 番号 11, 1995, p. 3437-3445.

研究成果: Article

Matsumura, Shuichi ; Shimura, Yukimasa ; Toshima, Kazunobu ; Tsuji, Masao ; Hatanaka, Tadashi. / Molecular design of biodegradable functional polymers, 4 Poly(vinyl alcohol) block as biodegradable segment. :: Macromolecular Chemistry and Physics. 1995 ; 巻 196, 番号 11. pp. 3437-3445.
@article{f9066c3d4d3a4617a1fef3f9873fd841,
title = "Molecular design of biodegradable functional polymers, 4 Poly(vinyl alcohol) block as biodegradable segment",
abstract = "The minimum structure of a poly(vinyl alcohol) block as a biodegradable segment in the polymer chain was estimated with respect to block length and its stereochemical configuration. It was found that poly(vinyl alcohol) block with a chain length of more than 3 monomeric units and having an isotactic structure is quickly biodegraded, in contrast to an atactic block having the same chain length, by poly(vinyl alcohol) (PVA) assimilating microbes and PVA‐dehydrogenase. It was also found that the substrate specificity of PVA‐dehydrogenase obtained from both Alcaligenes faecalis KK314 and Pseudomonas sp. 113 P3 is quite similar.",
author = "Shuichi Matsumura and Yukimasa Shimura and Kazunobu Toshima and Masao Tsuji and Tadashi Hatanaka",
year = "1995",
doi = "10.1002/macp.1995.021961101",
language = "English",
volume = "196",
pages = "3437--3445",
journal = "Macromolecular Chemistry and Physics",
issn = "1022-1352",
publisher = "Wiley-VCH Verlag",
number = "11",

}

TY - JOUR

T1 - Molecular design of biodegradable functional polymers, 4 Poly(vinyl alcohol) block as biodegradable segment

AU - Matsumura, Shuichi

AU - Shimura, Yukimasa

AU - Toshima, Kazunobu

AU - Tsuji, Masao

AU - Hatanaka, Tadashi

PY - 1995

Y1 - 1995

N2 - The minimum structure of a poly(vinyl alcohol) block as a biodegradable segment in the polymer chain was estimated with respect to block length and its stereochemical configuration. It was found that poly(vinyl alcohol) block with a chain length of more than 3 monomeric units and having an isotactic structure is quickly biodegraded, in contrast to an atactic block having the same chain length, by poly(vinyl alcohol) (PVA) assimilating microbes and PVA‐dehydrogenase. It was also found that the substrate specificity of PVA‐dehydrogenase obtained from both Alcaligenes faecalis KK314 and Pseudomonas sp. 113 P3 is quite similar.

AB - The minimum structure of a poly(vinyl alcohol) block as a biodegradable segment in the polymer chain was estimated with respect to block length and its stereochemical configuration. It was found that poly(vinyl alcohol) block with a chain length of more than 3 monomeric units and having an isotactic structure is quickly biodegraded, in contrast to an atactic block having the same chain length, by poly(vinyl alcohol) (PVA) assimilating microbes and PVA‐dehydrogenase. It was also found that the substrate specificity of PVA‐dehydrogenase obtained from both Alcaligenes faecalis KK314 and Pseudomonas sp. 113 P3 is quite similar.

UR - http://www.scopus.com/inward/record.url?scp=0009353428&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0009353428&partnerID=8YFLogxK

U2 - 10.1002/macp.1995.021961101

DO - 10.1002/macp.1995.021961101

M3 - Article

AN - SCOPUS:0009353428

VL - 196

SP - 3437

EP - 3445

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1022-1352

IS - 11

ER -