Investigations revealed that N-Benzyl-N-(2-methoxyphenyl)cyclo-hex-1-enecarboxamide did not photocyclize in the solid state. The methoxy group was involved in intermolecular steric interactions and so prevented the rotation of the N-phenyl group in the crystal. N-Benzyl-N-(2-methoxyphenyl)cyclo-hex-1-enecarboxamide was prepared under a study on photocyclization of enamides and thioamides in the solid state and crystals were grown from a hexane solution.
|ジャーナル||Acta Crystallographica Section C: Crystal Structure Communications|
|出版ステータス||Published - 2000 1 1|
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