New insight into reaction of iron(III)-peroxide adduct with alkanes: An alternative model for cytochrome P-450 and methane monooxygenase

Yuzo Nishida, Sayo Ito, Takashi Okuno, Shigeru Ohba

研究成果: Article査読

9 被引用数 (Scopus)

抄録

A new mechanism for alkane functionalization by iron(III)-peroxide adducts was proposed, and the importance of electrophilic nature of the metal-peroxide adduct with η1-coordination mode was emphasized. This idea suggests that formation of high-valent iron-oxo species occurs most likely when the metal-peroxide intermediate is activated through electronic interaction with both the peripheral organic group and substrate; the latter two act as an electron donor to the peroxide adduct.

本文言語English
ページ(範囲)615-622
ページ数8
ジャーナルZeitschrift fur Naturforschung Section C - Journal of Biosciences
52
9-10
DOI
出版ステータスPublished - 1997

ASJC Scopus subject areas

  • 生化学、遺伝学、分子生物学(全般)

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