New protocol for the siteselective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions

Fumitoshi Kakiuchi, Taisuke Sato, Takuya Tsujimoto, Masakazu Yamauchi, Naoto Chatani, Shinji Murai

研究成果: Article査読

80 被引用数 (Scopus)

抄録

Catalyst-specific C-H/olefin as well as C-H/acetylene coupling has been accomplished for aromatics which contain both keto and imino substituents by simply changing the catalyst. By using Ru(H)2(CO)(PPh3)3 as the catalyst, the C-H bond at the position ortho to the carbonyl group reacted to add across an olefin. When Ru3(CO)12 is used as the catalyst, the C-H bond at the position ortho to the imino group reacted with the olefin.

本文言語English
ページ(範囲)1053-1054
ページ数2
ジャーナルChemistry Letters
10
DOI
出版ステータスPublished - 1998 1月 1
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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