Nondissociative chain walking as a strategy in catalytic organic synthesis

Takuya Kochi; Shota Kanno; Fumitoshi Kakiuchi

doi:10.1016/j.tetlet.2019.07.029

Nondissociative chain walking as a strategy in catalytic organic synthesis

Takuya Kochi, Shota Kanno, Fumitoshi Kakiuchi

化学科

研究成果: Review article › 査読

15 被引用数 (Scopus)

抄録

“Nondissociative” chain walking is a mechanism where an alkylmetal species undergoes rapid β-hydride elimination and reinsertion to move the metal center along the alkyl chain without dissociating an alkene intermediate during the migration process. This digest summarizes the unique characteristics of the nondissociative chain walking mechanism compared to the stepwise alkene isomerization mechanism and their use in catalytic organic synthesis.

本文言語	English
論文番号	150938
ジャーナル	Tetrahedron Letters
巻	60
号	37
DOI	https://doi.org/10.1016/j.tetlet.2019.07.029
出版ステータス	Published - 2019 9 12

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

文献へのアクセス

10.1016/j.tetlet.2019.07.029

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引用スタイル

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AB - “Nondissociative” chain walking is a mechanism where an alkylmetal species undergoes rapid β-hydride elimination and reinsertion to move the metal center along the alkyl chain without dissociating an alkene intermediate during the migration process. This digest summarizes the unique characteristics of the nondissociative chain walking mechanism compared to the stepwise alkene isomerization mechanism and their use in catalytic organic synthesis.

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KW - Remote functionalization

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