Nondissociative chain walking as a strategy in catalytic organic synthesis

研究成果: Review article査読

15 被引用数 (Scopus)

抄録

“Nondissociative” chain walking is a mechanism where an alkylmetal species undergoes rapid β-hydride elimination and reinsertion to move the metal center along the alkyl chain without dissociating an alkene intermediate during the migration process. This digest summarizes the unique characteristics of the nondissociative chain walking mechanism compared to the stepwise alkene isomerization mechanism and their use in catalytic organic synthesis.

本文言語English
論文番号150938
ジャーナルTetrahedron Letters
60
37
DOI
出版ステータスPublished - 2019 9 12

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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