抜粋
“Nondissociative” chain walking is a mechanism where an alkylmetal species undergoes rapid β-hydride elimination and reinsertion to move the metal center along the alkyl chain without dissociating an alkene intermediate during the migration process. This digest summarizes the unique characteristics of the nondissociative chain walking mechanism compared to the stepwise alkene isomerization mechanism and their use in catalytic organic synthesis.
| 元の言語 | English |
|---|---|
| 記事番号 | 150938 |
| ジャーナル | Tetrahedron Letters |
| 巻 | 60 |
| 発行部数 | 37 |
| DOI | |
| 出版物ステータス | Published - 2019 9 12 |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
フィンガープリント Nondissociative chain walking as a strategy in catalytic organic synthesis' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Kochi, T., Kanno, S., & Kakiuchi, F. (2019). Nondissociative chain walking as a strategy in catalytic organic synthesis. Tetrahedron Letters, 60(37), [150938]. https://doi.org/10.1016/j.tetlet.2019.07.029