@article{88c5ca3fcbdf4ffc929dcc978abf36b3,
title = "Nondissociative chain walking as a strategy in catalytic organic synthesis",
abstract = "“Nondissociative” chain walking is a mechanism where an alkylmetal species undergoes rapid β-hydride elimination and reinsertion to move the metal center along the alkyl chain without dissociating an alkene intermediate during the migration process. This digest summarizes the unique characteristics of the nondissociative chain walking mechanism compared to the stepwise alkene isomerization mechanism and their use in catalytic organic synthesis.",
keywords = "Isomerization, Metal catalysis, Nondissociative chain walking, Remote functionalization",
author = "Takuya Kochi and Shota Kanno and Fumitoshi Kakiuchi",
note = "Funding Information: This work was supported, in part, by JSPS KAKENHI Grant Numbers JP18H01985 (Grant-in-Aid for Scientific Research (B)), JP15KT0069 (Grant-in-Aid for Scientific Research (B)) and JP18H04271 (Precisely Designed Catalysts with Customized Scaffolding) and the Asahi Glass Foundation . Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",
year = "2019",
month = sep,
day = "12",
doi = "10.1016/j.tetlet.2019.07.029",
language = "English",
volume = "60",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "37",
}