Novel 1,2-cis-stereoselective glycosylations utilizing organoboron reagents and their application to natural products and complex oligosaccharide synthesis

Daisuke Takahashi, Masamichi Tanaka, Nobuya Nishi, Kazunobu Toshima

研究成果: Article査読

24 被引用数 (Scopus)

抄録

In this mini-review article, 1,2-cis-stereoselective glycosylation methods utilizing organoboron reagents and 1,2-anhydroglycosyl donors that were developed in our laboratory, including regio- and 1,2-cis-stereoselective glycosylations using glycosyl-acceptor-derived boronic ester catalysts and 1,2-cis-stereoselective glycosylations using glycosyl-acceptor-derived borinic ester catalysts, are recounted. Representative applications of these methods to the synthesis of biologically active natural products and a complex oligosaccharide are also described.

本文言語English
ページ(範囲)64-77
ページ数14
ジャーナルCarbohydrate Research
452
DOI
出版ステータスPublished - 2017 11月 27

ASJC Scopus subject areas

  • 分析化学
  • 生化学
  • 有機化学

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