Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst

Shuichi Matsumura; Eiya Yao; Kazuya Sakiyama; Kazunobu Toshima

doi:10.1246/cl.1999.373

Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst

Shuichi Matsumura, Eiya Yao, Kazuya Sakiyama, Kazunobu Toshima

応用化学科

研究成果: Article › 査読

4 被引用数 (Scopus)

抄録

n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C₄GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C₄GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.

本文言語	English
ページ（範囲）	373-374
ページ数	2
ジャーナル	Chemistry Letters
号	5
DOI	https://doi.org/10.1246/cl.1999.373
出版ステータス	Published - 1999 1月 1

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化学 (全般)

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10.1246/cl.1999.373

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abstract = "n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C4GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C4GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.",

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T1 - Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst

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AU - Yao, Eiya

AU - Sakiyama, Kazuya

AU - Toshima, Kazunobu

PY - 1999/1/1

Y1 - 1999/1/1

N2 - n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C4GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C4GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.

AB - n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C4GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C4GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.

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JO - Chemistry Letters

JF - Chemistry Letters

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Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst

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