N2O oxidation of phosphines catalyzed by low-valent nickel complexes

Tohru Yamada; Kyosuke Suzuki; Kentaro Hashimoto; Taketo Ikeno

doi:10.1246/cl.1999.1043

N₂O oxidation of phosphines catalyzed by low-valent nickel complexes

Tohru Yamada, Kyosuke Suzuki, Kentaro Hashimoto, Taketo Ikeno

化学科

研究成果: Article › 査読

26 被引用数 (Scopus)

抄録

In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)₂ or NiCl₂ with DIBAL or BuLi, nitrous oxide (N₂O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N₂O; oxidation and were recovered after the reaction.

本文言語	English
ページ（範囲）	1043-1044
ページ数	2
ジャーナル	Chemistry Letters
号	10
DOI	https://doi.org/10.1246/cl.1999.1043
出版ステータス	Published - 1999

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/cl.1999.1043

他のファイルとリンク

引用スタイル

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abstract = "In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)2 or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N2O; oxidation and were recovered after the reaction.",

author = "Tohru Yamada and Kyosuke Suzuki and Kentaro Hashimoto and Taketo Ikeno",

year = "1999",

doi = "10.1246/cl.1999.1043",

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journal = "Chemistry Letters",

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AU - Suzuki, Kyosuke

AU - Hashimoto, Kentaro

AU - Ikeno, Taketo

PY - 1999

Y1 - 1999

N2 - In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)2 or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N2O; oxidation and were recovered after the reaction.

AB - In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)2 or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N2O; oxidation and were recovered after the reaction.

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