Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

Makoto Mitani; Kunihiro Oouchi; Michiya Hayakawa; Tohru Yamada; Teruaki Mukaiyama

doi:10.1007/BF00294949

Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

Makoto Mitani, Kunihiro Oouchi, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

研究成果: Article › 査読

18 被引用数 (Scopus)

抄録

Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

本文言語	English
ページ（範囲）	677-682
ページ数	6
ジャーナル	Polymer Bulletin
巻	35
号	6
DOI	https://doi.org/10.1007/BF00294949
出版ステータス	Published - 1995 12月 1
外部発表	はい

ASJC Scopus subject areas

化学 (全般)
凝縮系物理学
ポリマーおよびプラスチック
材料化学

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abstract = "Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.",

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AU - Mitani, Makoto

AU - Oouchi, Kunihiro

AU - Hayakawa, Michiya

AU - Yamada, Tohru

AU - Mukaiyama, Teruaki

PY - 1995/12/1

Y1 - 1995/12/1

N2 - Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

AB - Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

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Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

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