Optically active β-ketoiminato cationic cobalt(III) complexes: Efficient catalysts for enantioselective carbonyl-ene reaction of glyoxal derivatives

Satoko Kezuka, Taketo Ikeno, Tohru Yamada

研究成果: Article

62 引用 (Scopus)

抜粋

(formula presented) Optically active β-ketoiminato cationic cobalt(III) complexes were synthesized as effective Lewis acid catalysts for the enantioselective carbonyl-ene reaction. In the presence of a catalytic amount of cobalt(III) hexafluoroantimonate derived from the optically active 1,2-diphenyl-1,2-ethanediamine, the carbonyl-ene reaction with a variety of alkenes and glyoxal derivatives smoothly proceeded to afford the corresponding homoallylic alcohols in good-to-high yields with high enantioselectivities.

元の言語English
ページ(範囲)1937-1939
ページ数3
ジャーナルOrganic Letters
3
発行部数12
DOI
出版物ステータスPublished - 2001 6 14

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

フィンガープリント Optically active β-ketoiminato cationic cobalt(III) complexes: Efficient catalysts for enantioselective carbonyl-ene reaction of glyoxal derivatives' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用