Optically active β-ketoiminato manganese(III) complexes as efficient catalysts in enantioselective aerobic epoxidation of unfunctionalized olefins

Takushi Nagata, Kiyomi Imagawa, Tohru Yamada, Teruaki Mukaiyama

研究成果: Article査読

28 被引用数 (Scopus)

抄録

A novel manganese(III) complex having an optically active N, N′-ethylenebis-β-ketoimine ligand was prepared and characterized crystallographically. The manganese(III) complexes behave as effective catalysts in enantioselective epoxidation of unfunctionalized olefins by combined use of molecular oxygen, an oxidant, and pivalaldehyde, a reductant. Dihydronaphthalene derivatives were converted into the corresponding optically active epoxides with good to high enantioselectivities.

本文言語English
ページ(範囲)283-287
ページ数5
ジャーナルInorganica Chimica Acta
220
1-2
DOI
出版ステータスPublished - 1994 6 1
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

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