Oriented chlorine atoms as a probe of the nonadiabatic photodissociation dynamics of molecular chlorine

Andrew J. Alexander, Zee Hwan Kim, S. Alex Kandel, Richard N. Zare, T. Peter Rakitzis, Yukako Asano, Satoshi Yabushita

研究成果: Article査読

55 被引用数 (Scopus)

抄録

Molecular chlorine was photodissociated at 310 and 330 nm using circularly polarized light. Orientation moments of the electronic angular momentum of product ground-state Cl(2P3/2) and excited-state Cl*(2P1/2) chlorine atoms were measured and the contributions from both coherent and incoherent dissociation mechanisms were resolved. The experimental results for Cl* can be explained by nonadiabatic transitions from the C 1Π1u state to higher states of 1u symmetry, induced by noncrossing-type radial derivative coupling.

本文言語English
ページ(範囲)9022-9031
ページ数10
ジャーナルJournal of Chemical Physics
113
20
DOI
出版ステータスPublished - 2000 11

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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