Oriented chlorine atoms as a probe of the nonadiabatic photodissociation dynamics of molecular chlorine

Andrew J. Alexander; Zee Hwan Kim; S. Alex Kandel; Richard N. Zare; T. Peter Rakitzis; Yukako Asano; Satoshi Yabushita

doi:10.1063/1.1319995

Oriented chlorine atoms as a probe of the nonadiabatic photodissociation dynamics of molecular chlorine

Andrew J. Alexander, Zee Hwan Kim, S. Alex Kandel, Richard N. Zare, T. Peter Rakitzis, Yukako Asano, Satoshi Yabushita

研究成果: Article › 査読

55 被引用数 (Scopus)

抄録

Molecular chlorine was photodissociated at 310 and 330 nm using circularly polarized light. Orientation moments of the electronic angular momentum of product ground-state Cl(²P_3/2) and excited-state Cl*(²P_1/2) chlorine atoms were measured and the contributions from both coherent and incoherent dissociation mechanisms were resolved. The experimental results for Cl* can be explained by nonadiabatic transitions from the C ¹Π_1u state to higher states of 1_u symmetry, induced by noncrossing-type radial derivative coupling.

本文言語	English
ページ（範囲）	9022-9031
ページ数	10
ジャーナル	Journal of Chemical Physics
巻	113
号	20
DOI	https://doi.org/10.1063/1.1319995
出版ステータス	Published - 2000 11月
外部発表	はい

ASJC Scopus subject areas

物理学および天文学（全般）
物理化学および理論化学

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10.1063/1.1319995

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title = "Oriented chlorine atoms as a probe of the nonadiabatic photodissociation dynamics of molecular chlorine",

abstract = "Molecular chlorine was photodissociated at 310 and 330 nm using circularly polarized light. Orientation moments of the electronic angular momentum of product ground-state Cl(2P3/2) and excited-state Cl*(2P1/2) chlorine atoms were measured and the contributions from both coherent and incoherent dissociation mechanisms were resolved. The experimental results for Cl* can be explained by nonadiabatic transitions from the C 1Π1u state to higher states of 1u symmetry, induced by noncrossing-type radial derivative coupling.",

author = "Alexander, {Andrew J.} and Kim, {Zee Hwan} and Kandel, {S. Alex} and Zare, {Richard N.} and Rakitzis, {T. Peter} and Yukako Asano and Satoshi Yabushita",

year = "2000",

month = nov,

doi = "10.1063/1.1319995",

language = "English",

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T1 - Oriented chlorine atoms as a probe of the nonadiabatic photodissociation dynamics of molecular chlorine

AU - Alexander, Andrew J.

AU - Kim, Zee Hwan

AU - Kandel, S. Alex

AU - Zare, Richard N.

AU - Rakitzis, T. Peter

AU - Asano, Yukako

AU - Yabushita, Satoshi

PY - 2000/11

Y1 - 2000/11

N2 - Molecular chlorine was photodissociated at 310 and 330 nm using circularly polarized light. Orientation moments of the electronic angular momentum of product ground-state Cl(2P3/2) and excited-state Cl*(2P1/2) chlorine atoms were measured and the contributions from both coherent and incoherent dissociation mechanisms were resolved. The experimental results for Cl* can be explained by nonadiabatic transitions from the C 1Π1u state to higher states of 1u symmetry, induced by noncrossing-type radial derivative coupling.

AB - Molecular chlorine was photodissociated at 310 and 330 nm using circularly polarized light. Orientation moments of the electronic angular momentum of product ground-state Cl(2P3/2) and excited-state Cl*(2P1/2) chlorine atoms were measured and the contributions from both coherent and incoherent dissociation mechanisms were resolved. The experimental results for Cl* can be explained by nonadiabatic transitions from the C 1Π1u state to higher states of 1u symmetry, induced by noncrossing-type radial derivative coupling.

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DO - 10.1063/1.1319995

M3 - Article

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VL - 113

SP - 9022

EP - 9031

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 20

ER -

Oriented chlorine atoms as a probe of the nonadiabatic photodissociation dynamics of molecular chlorine

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