抄録
Molecular chlorine was photodissociated at 310 and 330 nm using circularly polarized light. Orientation moments of the electronic angular momentum of product ground-state Cl(2P3/2) and excited-state Cl*(2P1/2) chlorine atoms were measured and the contributions from both coherent and incoherent dissociation mechanisms were resolved. The experimental results for Cl* can be explained by nonadiabatic transitions from the C 1Π1u state to higher states of 1u symmetry, induced by noncrossing-type radial derivative coupling.
本文言語 | English |
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ページ(範囲) | 9022-9031 |
ページ数 | 10 |
ジャーナル | Journal of Chemical Physics |
巻 | 113 |
号 | 20 |
DOI | |
出版ステータス | Published - 2000 11月 |
外部発表 | はい |
ASJC Scopus subject areas
- 物理学および天文学(全般)
- 物理化学および理論化学