TY - JOUR
T1 - Oxidation of cyclohexane with hydrogen peroxide catalysed by copper(II) complexes containing N,N-bis(2-pyridylmethyl)-β-alanineamide ligands
AU - Okuno, Takashi
AU - Ohba, Shigeru
AU - Nishida, Yuzo
PY - 1997/1/1
Y1 - 1997/1/1
N2 - In the presence of hydrogen peroxide, a mononuclear copper(II) complex, [Cu(bdpg)Cl]Cl [where (bdpg) represents N,N-bis(2-pyridylmethyl)-β-alanine-amide] exhibits a much higher activity for the oxygenation of cyclohexane than other analogs. Crystal structure determinations and spectroscopic data indicate that the amide group in the (bdpg) ligand, which can interact with a hydroperoxide-ion η1-bonded to copper(II) plays an important role in activation of hydrogen peroxide, leading to the facile oxygenation of cyclohexane.
AB - In the presence of hydrogen peroxide, a mononuclear copper(II) complex, [Cu(bdpg)Cl]Cl [where (bdpg) represents N,N-bis(2-pyridylmethyl)-β-alanine-amide] exhibits a much higher activity for the oxygenation of cyclohexane than other analogs. Crystal structure determinations and spectroscopic data indicate that the amide group in the (bdpg) ligand, which can interact with a hydroperoxide-ion η1-bonded to copper(II) plays an important role in activation of hydrogen peroxide, leading to the facile oxygenation of cyclohexane.
KW - Hydrogen peroxide
KW - Monomeric copper(II) complex
KW - Oxygenation by copper(II) complex
KW - Oxygenation of cyclohexane
KW - Tripodal-ligands
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U2 - 10.1016/S0277-5387(97)00147-2
DO - 10.1016/S0277-5387(97)00147-2
M3 - Article
AN - SCOPUS:0039331399
VL - 16
SP - 3765
EP - 3774
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 21
ER -