Palladium-catalyzed regioselective homocoupling of arenes using anodic oxidation: Formal electrolysis of aromatic carbon-hydrogen bonds

Fumito Saito, Hiroko Aiso, Takuya Kochi, Fumitoshi Kakiuchi

研究成果: Article査読

69 被引用数 (Scopus)

抄録

Palladium-catalyzed regioselective homocoupling of arylpyridines under anodic oxidation conditions was achieved in the presence of I2. The dimerization of meta-substituted arylpyridines proceeded selectively at less-sterically congested ortho-positions, and the selectivity is different from that reported for the palladium-catalyzed dimerization using Oxone as an oxidant. The dimerization also proceeds using catalytic amounts of both Pd(OAc)2 and I2 under the electrochemical reaction conditions.

本文言語English
ページ(範囲)6704-6707
ページ数4
ジャーナルOrganometallics
33
22
DOI
出版ステータスPublished - 2014 11 24

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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