Palladium-Catalyzed Remote Diborylative Cyclization of Dienes with Diborons via Chain Walking

研究成果: Article査読

抄録

A novel method for catalytic remote bismetalation of alkene substrates by the addition of dimetal reagents is accomplished by using chain walking. In the presence of a palladium catalyst, the reaction of various 1,n-dienes and diborons were converted into cyclopentane derivatives with two boryl groups at remote positions via facile regioselective transformation of an unactivated sp3 C-H bond to a C-B bond. Sequential construction of three distant bonds, which is difficult to achieve by any method, was accomplished for the reactions of 1,n-dienes (n ≥ 7).

本文言語English
ページ(範囲)19275-19281
ページ数7
ジャーナルJournal of the American Chemical Society
143
46
DOI
出版ステータスPublished - 2021 11 24

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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