Phenyltrichlorogermane synthesis by the reaction of chlorobenzene and the dichlorogermylene intermediate formed from elemental germanium and tetrachlorogermane

Masaki Okamoto, Takuya Asano, Eiichi Suzuki

研究成果: Article査読

8 被引用数 (Scopus)

抄録

Phenyltrichlorogermane was synthesized with high selectivity, 96%, from elemental germanium, tetrachlorogermane, and chlorobenzene using no catalyst, almost all germanium and tetrachlorogermane being converted. Dichlorogermylene was formed as a reaction intermediate by the reaction of germanium with tetrachlorogermane and inserted into the C-Cl bond of chlorobenzene to yield phenyltrichlorogermane.

本文言語English
ページ(範囲)5583-5585
ページ数3
ジャーナルOrganometallics
20
26
DOI
出版ステータスPublished - 2001 12 24
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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