Photocatalytic reactions of acetic acid on platinum-loaded TiO2: ESR evidence of radical intermediates in the photo-Kolbe reaction

M. Kaise; H. Kondoh; C. Nishihara; H. Nozoye; H. Shindo; S. Nimura; O. Kikuchi

doi:10.1039/C39930000395

Photocatalytic reactions of acetic acid on platinum-loaded TiO₂: ESR evidence of radical intermediates in the photo-Kolbe reaction

M. Kaise, H. Kondoh, C. Nishihara, H. Nozoye, H. Shindo, S. Nimura, O. Kikuchi

研究成果: Article › 査読

12 被引用数 (Scopus)

抄録

Two elusive radical intermediates; a methyl radical (·CH ₃) and a carboxymethyl radical (·CH₂CO ₂H), have been confirmed for the first time by direct observation of their ESR absorptions at room temperature on the photocatalytic reactions of acetic acid and metal (platinum)-loaded titanium dioxide (Pt/TiO₂) in aqueous solution.

本文言語	English
ページ（範囲）	395-396
ページ数	2
ジャーナル	Journal of the Chemical Society, Chemical Communications
号	4
DOI	https://doi.org/10.1039/C39930000395
出版ステータス	Published - 1993 12月 1
外部発表	はい

ASJC Scopus subject areas

分子医療

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10.1039/C39930000395

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引用スタイル

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AU - Nimura, S.

AU - Kikuchi, O.

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