Photoelectron spectroscopy of silicon-carbon cluster anions (Si nCm -)

Atsushi Nakajima, Tetsuya Taguwa, Kojiro Nakao, Motoki Gomei, Reiko Kishi, Suehiro Iwata, Koji Kaya

研究成果: Article

81 引用 (Scopus)

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Photoelectron spectra of Sin,Cm - cluster anions (1≤n≤7 and 1≤m≤5) were measured at the photon energies of 3.49 eV, by using a magnetic bottle electron spectrometer. The Si nCm - clusters were produced either by a laser vaporization of a silicon-carbon mixed rod or by two laser vaporizations of carbon and silicon rods in a He carrier gas. The spectra of the Si nC1 - (3≤n≤7) clusters are similar to those of pure Sin+1 - clusters in the peak positions and their envelopes, which is attributed to the isovalent electronic structure of Si and C atoms as well as to the similar geometrical structure. In contrast, the similarity in the photoelectron spectra is not observed between Cm+1 and Si1Cm (2≤m≤5) clusters, which is attributed to a change in their geometry; from chain to ring. These experimental conclusions are discussed with the results of our theoretical calculations.

元の言語English
ページ(範囲)2050-2057
ページ数8
ジャーナルThe Journal of Chemical Physics
103
発行部数6
DOI
出版物ステータスPublished - 1995 1 1

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

フィンガープリント Photoelectron spectroscopy of silicon-carbon cluster anions (Si <sub>n</sub>C<sub>m</sub> <sup>-</sup>)' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Nakajima, A., Taguwa, T., Nakao, K., Gomei, M., Kishi, R., Iwata, S., & Kaya, K. (1995). Photoelectron spectroscopy of silicon-carbon cluster anions (Si nCm -). The Journal of Chemical Physics, 103(6), 2050-2057. https://doi.org/10.1063/1.469731