Photoexcited State Confinement in Two-Dimensional Crystalline Anthracene Monolayer at Room Temperature

Masahiro Shibuta, Naoyuki Hirata, Toyoaki Eguchi, Atsushi Nakajima

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Organic thin film electronics place a high demand on bottom-up technology to form a two-dimensionally (2D) functional unit consisting of a single molecular crystalline layer bound to a layered structure. As the strong interaction between a substrate and molecules makes it difficult to evaluate the electronic properties of organic films, the nature of electronic excited states has not been elucidated. Here, we study a 2D crystalline anthracene monolayer electronically decoupled by alkanethiolates on a gold substrate using scanning tunneling microscopy and time-resolved two-photon photoemission spectroscopy and unravel the geometric/electronic structures and excited electron dynamics. Our data reveal that dispersive 2D excited electrons on the surface can be highly coupled with an annihilation of nondispersive excitons that facilitate electron emission with vibronic interaction. Our results provide a fundamental framework for understanding photoexcited anthracene monolayer and show how the coupling between dispersive and nondispersive excited states may assist charge separation in crystalline molecular layers.

本文言語English
ページ(範囲)4307-4314
ページ数8
ジャーナルACS Nano
11
4
DOI
出版ステータスPublished - 2017 4月 25

ASJC Scopus subject areas

  • 材料科学(全般)
  • 工学(全般)
  • 物理学および天文学(全般)

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