Photoinduced magnetization of the cyano-bridged 3d-4f heterobimetallic assembly Nd(DMF)4(H2O)3(μ-CN)Fe(CN) 5·H2O (DMF = N,N-dimethylformamide)

Guangming Li, Takashiro Akitsu, Osamu Sato, Yasuaki Einaga

研究成果: Article査読

125 被引用数 (Scopus)

抄録

Photoinduced magnetization of the cyano-bridged 3d-4f heterobimetallic assembly Nd(DMF)4(H2O)3(μ-CN)Fe(CN)5·H2O (1) (DMF = N,N-dimethylformamide) is described in this paper. The χMT values are enhanced by about 45% after UV light illumination in the temperature range of 5-50 K. We propose that UV light illumination induces a structural distortion in 1. This small structural change is propagated by molecular interactions in the inorganic network. Furthermore, the cooperativity resulting from the molecular interaction functions to increase the activation energy of the relaxation processes, which makes observation of the photoexcited state possible. The flexible network structure through the hydrogen bonds in 1 plays an essential role for the photoinduced phenomenon. This finding may open up a new domain for developing the molecule-based magnetic materials.

本文言語English
ページ(範囲)12396-12397
ページ数2
ジャーナルJournal of the American Chemical Society
125
41
DOI
出版ステータスPublished - 2003 10 15

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

フィンガープリント

「Photoinduced magnetization of the cyano-bridged 3d-4f heterobimetallic assembly Nd(DMF)<sub>4</sub>(H<sub>2</sub>O)<sub>3</sub>(μ-CN)Fe(CN) <sub>5</sub>·H<sub>2</sub>O (DMF = N,N-dimethylformamide)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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