Photophysics and electrochemistry of ruthenium complexes for electrogenerated chemiluminescence

Elena Villani, Kohei Sakanoue, Yasuaki Einaga, Shinsuke Inagi, Andrea Fiorani

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Electrogenerated chemiluminescence, or electrochemiluminescence (ECL), is nowadays a powerful transduction method in electroanalysis, in particular regarding the application in clinical diagnostics. Indeed, its superior capability relies in the fruitful combination of electrochemical and photoluminescence properties. The research on efficient ECL luminophores has brought a wide range of molecules, form organic systems to inorganic complexes, however, despite this large pool of luminophores available, tris(2,2′-bipyridine)ruthenium (II) [Ru(bpy)3]2+ is still leading since the first report in 1972, in both academic research and commercially available systems. To acknowledge the outmost importance of this inorganic complex, here we report the photophysical and electrochemical properties of [Ru(bpy)3]2+ and its derivatives obtained by ligand design for application in ECL.

本文言語English
論文番号116677
ジャーナルJournal of Electroanalytical Chemistry
921
DOI
出版ステータスPublished - 2022 9月 15

ASJC Scopus subject areas

  • 分析化学
  • 化学工学(全般)
  • 電気化学

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