Practical and Rapid Vicinal Hydroxylation of Alkenes by Catalytic Ruthenium Tetraoxide

Tony K.M. Shing, Vincent W.‐F Tai, Eric K.W. Tam

研究成果: Article査読

149 被引用数 (Scopus)

抄録

Within minutes simple olefins, α,β‐unsaturated ketones and esters, allyl acetates, and allyl benzyl ethers can be cis‐dihydroxylated. The oxidation, an extension of Sharpless's method, is conducted with 0.07 equivalents of RuCl3·3H2O and 1.5 equivalents of NaIO4 in a two‐phase solvent system consisting of ethyl acetate, acetonitrile, and water at 0 °C! The low extent of diol cleavage and ketol formation is surprising.

本文言語English
ページ(範囲)2312-2313
ページ数2
ジャーナルAngewandte Chemie International Edition in English
33
22
DOI
出版ステータスPublished - 1994 12月 5

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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