Practical total synthesis of fuligocandins A and B

Midori A. Arai, Junya Seto, Firoj Ahmed, Kento Uchiyama, Masami Ishibashi

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Fuligocandins A and B, cycloanthranilylproline derivatives isolated from the myxomycete Fuligo candida, were synthesized efficiently by a Meyer-Schuster rearrangement, which gave Z-isomer with high selectivity. The absolute stereochemistry at C-11a of the natural products was determined to be S by comparison of the optical rotation of the natural products with synthetic counterparts derived from l-proline. This report is the first total synthesis of optically active fuligocandin B.

本文言語English
ページ(範囲)2498-2502
ページ数5
ジャーナルSynlett
16
DOI
出版ステータスPublished - 2010
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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