A series of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes have been prepared. The spin states of these complexes are presented as the admixed intermediate (S = 3/2, 5/2) on the basis of the 1H NMR, 13C NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.
ASJC Scopus subject areas
- 化学 (全般)