Programmed Self-Assembly of Branched Nanocrystals with an Amphiphilic Surface Pattern

Yuki Taniguchi, Muhammad Adli Bin Sazali, Yusei Kobayashi, Noriyoshi Arai, Tsuyoshi Kawai, Takuya Nakashima

研究成果: Article

10 引用 (Scopus)

抜粋

Site-selective surface modification on the shape-controlled nanocrystals is a key approach in the programmed self-assembly of inorganic colloidal materials. This study demonstrates a simple methodology to gain self-assemblies of semiconductor nanocrystals with branched shapes through tip-to-tip attachment. Short-chained water-soluble cationic thiols are employed as a surface ligand for CdSe tetrapods and CdSe/CdS core/shell octapods. Because of the less affinity of arm-tip to the surface ligands compared to the arm-side wall, the tip-surface becomes uncapped to give a hydrophobic nature, affording an amphiphilic surface pattern. The amphiphilic tetrapods aggregated into porous agglomerates through tip-to-tip connection in water, while they afforded a hexagonally arranged Kagome-like two-dimensional (2D) assembly by the simple casting of aqueous dispersion with the aid of a convective self-assembly mechanism. A 2D net-like assembly was similarly obtained from amphiphilic octapods. A dissipative particle dynamics simulation using a planar tripod model with an amphiphilic surface pattern reproduced the formation of the Kagome-like assembly in a 2D confined space, demonstrating that the lateral diffusion of nanoparticles and the firm contacts between the hydrophobic tips play crucial roles in the self-assembly.

元の言語English
ページ(範囲)9312-9320
ページ数9
ジャーナルACS Nano
11
発行部数9
DOI
出版物ステータスPublished - 2017 9 26
外部発表Yes

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ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

これを引用

Taniguchi, Y., Sazali, M. A. B., Kobayashi, Y., Arai, N., Kawai, T., & Nakashima, T. (2017). Programmed Self-Assembly of Branched Nanocrystals with an Amphiphilic Surface Pattern. ACS Nano, 11(9), 9312-9320. https://doi.org/10.1021/acsnano.7b04719