Redox reaction of Tris(acetylacetonato)iron(III) complex in an amide-type ionic liquid

Naoki Tachikawa, Ryo Haruyama, Kazuki Yoshii, Nobuyuki Serizawa, Yasushi Katayama

研究成果: Article査読

3 被引用数 (Scopus)

抄録

The redox reaction of tris(acetylacetonato)iron(III) (Fe(acac)3) on a glassy carbon electrode was investigated in 1- butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA). A one-electron transfer redox reaction of [Fe(acac)3]0/- showed the relatively negative potential of -1.4V vs. Ag|Ag(I). The diffusion coefficient of Fe(acac)3 estimated by chronoamperometry was (1.4 + 0.1) × 10-7cm2 s-1. The redox properties examined in this study suggested that the redox reaction of [Fe(acac)3]0/- can be utilized in the negative half-cell reaction of redox flow batteries.

本文言語English
ページ(範囲)32-34
ページ数3
ジャーナルElectrochemistry
86
2
DOI
出版ステータスPublished - 2018

ASJC Scopus subject areas

  • Electrochemistry

フィンガープリント 「Redox reaction of Tris(acetylacetonato)iron(III) complex in an amide-type ionic liquid」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル