Reduction of Acyl Enolates of α-Substituted β-Keto Esters by Bakers' Yeast

Hiromichi Ohta, Naoki Kobayashi, Takeshi Sugai

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Enol esters of 2-substituted-3-oxoalkanoates of (Z)-configuration were reduced by bakers' yeast to chiral 2-substituted-3-hydroxyalkanoates. The syn-selectivities of this reaction increased compared with those of the reduction of the corresponding racemic keto esters. The reaction may proceed via an asymmetric hydrolysis of the enol esters, followed by the reduction of the resulting carbonyl group.

本文言語English
ページ(範囲)489-493
ページ数5
ジャーナルAgricultural and biological chemistry
54
2
DOI
出版ステータスPublished - 1990

ASJC Scopus subject areas

  • 生化学、遺伝学、分子生物学(全般)
  • 農業および生物科学(全般)

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