Regiocontrolled copolymerization of methyl acrylate with carbon monoxide

Akifumi Nakamura, Kagehiro Munakata, Takuya Kochi, Kyoko Nozaki

研究成果: Article査読

37 被引用数 (Scopus)

抄録

An alternating copolymer of methyl acrylate with carbon monoxide has been synthesized for the first time via coordination polymerization using palladium complexes of phosphine-sulfonic acid as catalysts. The highly controlled head-to-tail structure of the copolymer was confirmed by NMR spectra. Subsequent insertion of carbon monoxide and methyl acrylate to methylpalladium species provided γ-ketoalkylpalladium 2. The present system apparently conquered the difficulty in coordination-insertion of CO to 2.

本文言語English
ページ(範囲)8128-8129
ページ数2
ジャーナルJournal of the American Chemical Society
130
26
DOI
出版ステータスPublished - 2008 7 2

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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