Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β-Acetoxy Elimination

Kazuma Muto, Takaaki Kumagai, Fumitoshi Kakiuchi, Takuya Kochi

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Palladium-catalyzed remote arylative substitution was achieved for the reaction of arylboronic acids with alkenes possessing a distant acetoxy group to provide arylation products having an alkene moiety at the remote position. The use of β-acetoxy elimination as a key step in the catalytic cycle allowed for regioselective formation of unstabilized alkenes after chain walking. This reaction was applicable to various arylboronic acids as well as alkene substrates.

本文言語English
ページ(範囲)24500-24504
ページ数5
ジャーナルAngewandte Chemie - International Edition
60
46
DOI
出版ステータスPublished - 2021 11月 8

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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