Reusable cobalt(III) complex catalysts for enantioselective borohydride reduction of ketones

Tatsuyuki Tsubo; Hsiu Hui Chen; Minako Yokomori; Satoshi Kikuchi; Tohru Yamada

doi:10.1246/bcsj.20130085

Reusable cobalt(III) complex catalysts for enantioselective borohydride reduction of ketones

Tatsuyuki Tsubo, Hsiu Hui Chen, Minako Yokomori, Satoshi Kikuchi, Tohru Yamada

化学科

研究成果: Article › 査読

5 被引用数 (Scopus)

抄録

A reusable catalytic system was developed for the catalytic enantioselective borohydride reduction of ketones. The optically active 1-chlorovinylketoiminatocobalt(III) complexes were recovered after the reaction by silica gel column chromatography, and then efficiently catalyzed the enantioselective reduction several times without any loss of reactivity as well as enantioselectivity.

本文言語	English
ページ（範囲）	983-986
ページ数	4
ジャーナル	Bulletin of the Chemical Society of Japan
巻	86
号	8
DOI	https://doi.org/10.1246/bcsj.20130085
出版ステータス	Published - 2013 8 29

ASJC Scopus subject areas

化学 (全般)

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10.1246/bcsj.20130085

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AU - Kikuchi, Satoshi

AU - Yamada, Tohru

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AB - A reusable catalytic system was developed for the catalytic enantioselective borohydride reduction of ketones. The optically active 1-chlorovinylketoiminatocobalt(III) complexes were recovered after the reaction by silica gel column chromatography, and then efficiently catalyzed the enantioselective reduction several times without any loss of reactivity as well as enantioselectivity.

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Reusable cobalt(III) complex catalysts for enantioselective borohydride reduction of ketones

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