Reversible chemical reactions as the basis for optical sensors used to detect amines, alcohols and humidity

Gerhard J. Mohr, Daniel Citterio, Caspar Demuth, Marc Fehlmann, Luzi Jenny, Christian Lohse, Allen Moradian, Tomas Nezel, Markus Rothmaier, Ursula E. Spichiger

研究成果: Article査読

56 被引用数 (Scopus)

抄録

A new class of indicator dyes for use in analytical chemistry is presented. In contrast to most existing indicator dyes, which change colour upon complexation or protonation/deprotonation, the dyes presented here perform reversible chemical reactions with the analyte, resulting in changes in absorbance or fluorescence. Specifically, azo and stilbene dyes which exhibit a reactive trifluoroacetyl group, reversibly interact with alcohols, amines or water to give the respective diol, hemiaminal, hemiacetal or zwitterion. Indicator dyes that combine the properties of a chemical reagent and a ligand molecule are termed 'chromo-' or 'fluororeactands'. They are embedded in various polymer materials and have been characterised for the optical sensing of aliphatic amines, alcohols and humidity. Furthermore, methacrylate derivatives of the dyes have been tested. They were prepared to link the dyes covalently to the polymer matrix. The optical and physical properties of the dye methacrylates make them promising candidates not only for optical sensing but also for applications in molecularly imprinted polymers and non-linear optics.

本文言語English
ページ(範囲)2259-2264
ページ数6
ジャーナルJournal of Materials Chemistry
9
9
DOI
出版ステータスPublished - 1999 1月 1
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 材料化学

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